While we use them when we refer to people, it is more in the sense of relationship than ownership.
Exercises - Possessive adjectives
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1) This is my mother's bag. It's her hers bag.
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2) Mine My coat is white.
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3) That is hers his shirt.
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4) He is mine my friend.
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5) It is yours your car.
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6) It is Mary's cat. It's hers her cat.
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7) These are our ours animals.
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8) This is our house. It's our ours house.
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9) This is their theirs book.
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10) Those are your yours cars.